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991.
Joseph B. Schlenoff W. Jack Rink Lawrence Seger 《Physica C: Superconductivity and its Applications》1991,180(5-6):387-393
Single crystals and polycrystalline pellets of the high-temperature cuprate superconductor Bi2Sr2Ca1Cu2O8 were doped at room temperature by electrochemical reduction at > 95% Coulombic efficiency using lithium dopant ions in propylene carbonate electrolyte. Cyclic voltammetry and potential step measurements on single crystals suggest an unusual reduction mechanism, with a diffusion coefficient for Li+ in the c-axis direction of bulk superconductor of ca. 3 × 10−11 cm2s−1. Sintered pellets of polycrystalline powder could be doped more rapidly, with an apparent diffusion coefficient of 7 × 10−8 cm2s−1. X-ray susceptibility analysis show extensive disordering occurs on heavy Li doping, with a first-order transition from a crystalline/superconducting to an amorphous/non-superconducting phase. Single, crystals of Bi2Sr2Ca1Cu2O8 exhibited a color change on reduction from metallic gray to golden bronze. The reduced material was highly air-sensitive, forming a hydroxide surface film on exposure to ambient atmosphere. 相似文献
992.
I. I. Antakov M. A. Moiseev E. V. Sokolov E. V. Zasypkin 《International Journal of Infrared and Millimeter Waves》1994,15(5):873-887
Using self-consistent field theory, the interaction of electron flow with HF fields in a gyroklystron has been analized. Optimal parameters of its output cavity corresponding to the maximum efficiency have been found. Experimental study of dependence of the efficiency on Q-factor and length of the output cavity has been carried out. The results of simulation are in good qualitative agreement with experimental data. 相似文献
993.
The transient absorption spectra of triphenylamine (TPA) in various solvents have beeninvestigated by the methods of nanosecond laser photolysis. The lifetimes of TPA were meas-ured. In hexane and ethanol, the transient absorptions of triplet state and triplet excimer ofTPA were observed. However, the transient absorptions of the TPA cation radical was alsoobserved in acetonitrile besides that of the triplet TPA monomer and excimer. According tothe experimental facts, the transient photophysical mechanism of TPA in various solvents hasbeen proposed. 相似文献
994.
Based on the stress transport model, a rate-dependent algebraic expression for the Reynolds stress tensor is developed. It is shown that the new model includes the normal stress effects and exhibits viscoelastic behavior. Furthermore, it is compatible with recently developed improved models of turbulence. The model is also consistent with the limiting behavior of turbulence in the inertial sublayer and is capable of predicting secondary flows in noncircular ducts. The TEACH code is modified according to the requirements of the rate-dependent model and is used to predict turbulent flow fields in a channel and behind a backward-facing step. The predicted results are compared with the available experimental data and those obtained from the standard k-ε and algebraic stress models. It is shown that the predictions of the new model are in better agreements with the experimental data. 相似文献
995.
In this note, we consider a class of two-point boundary value problems involving a pa- rameter in one of the boundary conditions. We shall show that if we know the solution corresponding to a particular value of the parameter, then the solution for any other value of the parameter can be obtained by a simple algebraic method. 相似文献
996.
本文提出一种利用材料Hugoniot数据研究高压下离子晶体中微观离子状态及其离子间排斥作用势的新方法。对氢化锂晶体进行研究时,我们得到Li~+和H~-离子之间排斥作用势函数,结果表明文献〔1〕中提出的离子压缩效应具有客观性。 相似文献
997.
Michaela Capellmann Hermann M. Bolt 《Fresenius' Journal of Analytical Chemistry》1992,342(4-5):462-466
Summary A reproducible method is described for the separation and simultaneous and specific quantitation of ascorbic acid and dehydroascorbic acid by ion-pairing reversed-phase HPLC with fluorometric detection. Copper sulphate and copper acetate were compared as oxidizing reagents for ascorbic acid and 1,2-diaminobenzene dihydrochloride and 1,2-diamino-3,4-dimethylbenzene dihydrochloride as derivatising reagents. The HPLC-method was applied to human plasma. The detection limit reaches 16 ng for ascorbic acid and 3 ng for dehydroascorbic acid. Sample preparation is carried out by solid phase extraction with a recovery of 98%; it is compared with conventional precipitation of plasma proteins by metaphosphoric acid. 相似文献
998.
Summary Oblique propagating magnetohydrodynamic waves with various wave forms and amplitudes are observed both at the Earth's foreshock
and at comets. The possibility of interpreting some observational results in terms of nonlinear evolution of one- and two-dimensional
hydromagnetic waves is investigated. For this purpose both analytical and numerical techniques are employed. It is found that
an initial monochromatic wave changes its polarization giving origin to magnetosonic shocks and rotational discontinuities;
the time evolution of density-magnetic-field correlation is studied, as a function of the plasma parameters and of the propagation
angle. In the two-dimensional case both a transverse instability and a self-focusing effect may take place. Moreover, a two-dimensional
magnetosonic solution is found, in which the density fluctuations are driven by the total pressure fluctuation as in a one-dimensional
simple wave. These theoretical predictions compare well with the features observed in the solar-wind waves.
Paper presented at the V Cosmic Physics National Conference, S. Miniato, November 27–30, 1990. 相似文献
999.
The reduction of chromate by glutathione, its mono- and diethyl esters,
-cysteine, 2-mercapto-propionic acid and mercapto-succinic acid has been studied. The empirical rate law kobs = ab[Thiol]2/(1 + b[Thiol]) is obeyed by all of these thiols, at neutral pH. No evidence could be obtained for a first-order pathway in glutathione under these conditions. These observations are used to comment on the stability of intermediates potentially important in explaining chromate toxicity. 相似文献
1000.